Study of quadrupole polarizabilities with combined configuration interaction and coupled-cluster method

The recently developed method combining the configuration interaction and the coupled-cluster method was demonstrated to provide accurate treatment of correlation corrections in divalent atomic systems [M.S.Safronova, M.G.Kozlov, and C.W.Clark, Phys. Rev. Lett. 107, 143006 (2011)]. We have extended this approach to the calculation of quadrupole polarizabilities alpha_2 and applied it to evaluate alpha_2 for the ground state of Mg and Mg-like Si^{2+}. Performing the calculations in three different approximations of increasing accuracy allowed us to place the upper bounds on the uncertainty of the final results. The recommended values alpha_2(3s^2 1S0)= 35.86(13) a.u. for Si^{2+} and alpha_2(3s^2 1S0)= 814(3) a.u. for Mg are estimated to be accurate to 0.37%. Differences in quadrupole polarizability contributions in neutral Mg and Si^{2+} ion are discussed.Comment: 6 pages, submitted to Phys. Rev.

Multipolar theory of black-body radiation shift of atomic energy levels and its implications for optical lattice clocks

A black-body radiation (BBR) shifts of (nsnp ^3P_0) - (ns^2 ^1S_0) clock transition in divalent atoms Mg, Ca, Sr, and Yb are evaluated. A theory of multipolar BBR shifts is developed and its implications are discussed. At room temperatures, the resulting uncertainties in the BBR shifts are relatively large and substantially affect the projected 10^{-18} fractional accuracy of the optical-lattice-based clocks.Comment: 4 pages, 1 figure, submitted to Physical Review Letter

Enhanced sensitivity to the fine-structure constant variation in Th IV atomic clock transition

Our calculations have shown that the 5f_5/2-7s_1/2 23131 cm^{-1} transition from the ground state in the ion Th^{3+} is very sensitive to the temporal variation of the fine structure constant alpha (q=-75300 cm^{-1}). The line is very narrow, the ion has been trapped and laser cooled and the positive shifter line 5f_5/2-5f_7/2 4325 cm^{-1} (q=+2900 cm^{-1}) may be used as a reference. A comparison may also be made with a positive shifter in another atom or ion. This makes Th^{3+} a good candidate to search for the alpha variation

Comment on "21-cm Radiation: A New Probe of Variation in the Fine-Structure Constant"

Khatri and Wandelt reported that change in the value of alpha by 1% changes the mean brightness temperature $T_b$ decrement of the CMB due to 21 cm absorption by 5% over the redshift range z $<$ 50. A drawback of their approach is that the dimensionful parameters are used. Changing of units leads to the change of the magnitude and even sign of the effect. Similar problems may be identified in a large number of other publications which consider limits on the variation of alpha using dimentionful parameters. We propose a method to obtain consistent results and provide an estimate of the effect.Comment: Added In v2: discussion of the effect of the variation of the fundamental constants on extracted numerical value of the barion-to-photon rati

Calculation of hyperfine structure constants for ytterbium

We calculate energies and hyperfine structure constants A and B for low-lying levels of $^{173}$Yb. The latter is treated as a two-electron atom. To account for valence-valence correlations the configuration interaction method is used. Valence-core correlations are accounted for within the many-body perturbation theory which is used to construct effective two-electron operators in the valence space.Comment: 8 pages, latex, iopart class or ioplppt style, submitted to J. Phys.